Algeria
- Population: 44700000
- Region: Africa
- Capital: Algiers
Angola
- Population: 32866268
- Region: Africa
- Capital: Luanda
Benin
- Population: 12123198
- Region: Africa
- Capital: Porto-Novo
Botswana
- Population: 2351625
- Region: Africa
- Capital: Gaborone
British Indian Ocean Territory
- Population: 3000
- Region: Africa
- Capital: Diego Garcia
Burkina Faso
- Population: 20903278
- Region: Africa
- Capital: Ouagadougou
Burundi
- Population: 11890781
- Region: Africa
- Capital: Gitega
Cameroon
- Population: 26545864
- Region: Africa
- Capital: Yaoundé
Cape Verde
- Population: 555988
- Region: Africa
- Capital: Praia
Central African Republic
- Population: 4829764
- Region: Africa
- Capital: Bangui
Chad
- Population: 16425859
- Region: Africa
- Capital: N'Djamena
Comoros
- Population: 869595
- Region: Africa
- Capital: Moroni
Djibouti
- Population: 988002
- Region: Africa
- Capital: Djibouti
DR Congo
- Population: 108407721
- Region: Africa
- Capital: Kinshasa
Egypt
- Population: 102334403
- Region: Africa
- Capital: Cairo
Equatorial Guinea
- Population: 1402985
- Region: Africa
- Capital: Malabo
Eritrea
- Population: 5352000
- Region: Africa
- Capital: Asmara
Eswatini
- Population: 1160164
- Region: Africa
- Capital: Mbabane
Ethiopia
- Population: 114963583
- Region: Africa
- Capital: Addis Ababa
Gabon
- Population: 2225728
- Region: Africa
- Capital: Libreville
Gambia
- Population: 2416664
- Region: Africa
- Capital: Banjul
Ghana
- Population: 31072945
- Region: Africa
- Capital: Accra
Guinea
- Population: 13132792
- Region: Africa
- Capital: Conakry
Guinea-Bissau
- Population: 1967998
- Region: Africa
- Capital: Bissau
Ivory Coast
- Population: 26378275
- Region: Africa
- Capital: Yamoussoukro
Kenya
- Population: 53771300
- Region: Africa
- Capital: Nairobi
Lesotho
- Population: 2142252
- Region: Africa
- Capital: Maseru
Liberia
- Population: 5057677
- Region: Africa
- Capital: Monrovia
Libya
- Population: 6871287
- Region: Africa
- Capital: Tripoli
Madagascar
- Population: 27691019
- Region: Africa
- Capital: Antananarivo
Malawi
- Population: 19129955
- Region: Africa
- Capital: Lilongwe
Mali
- Population: 20250834
- Region: Africa
- Capital: Bamako
Mauritania
- Population: 4649660
- Region: Africa
- Capital: Nouakchott
Mauritius
- Population: 1265740
- Region: Africa
- Capital: Port Louis
Mayotte
- Population: 226915
- Region: Africa
- Capital: Mamoudzou
Morocco
- Population: 36910558
- Region: Africa
- Capital: Rabat
Mozambique
- Population: 31255435
- Region: Africa
- Capital: Maputo
Namibia
- Population: 2540916
- Region: Africa
- Capital: Windhoek
Niger
- Population: 24206636
- Region: Africa
- Capital: Niamey
Nigeria
- Population: 206139587
- Region: Africa
- Capital: Abuja
Republic of the Congo
- Population: 5657000
- Region: Africa
- Capital: Brazzaville
Réunion
- Population: 840974
- Region: Africa
- Capital: Saint-Denis
Rwanda
- Population: 12952209
- Region: Africa
- Capital: Kigali
Saint Helena, Ascension and Tristan da Cunha
- Population: 53192
- Region: Africa
- Capital: Jamestown
São Tomé and Príncipe
- Population: 219161
- Region: Africa
- Capital: São Tomé
Senegal
- Population: 16743930
- Region: Africa
- Capital: Dakar
Seychelles
- Population: 98462
- Region: Africa
- Capital: Victoria
Sierra Leone
- Population: 7976985
- Region: Africa
- Capital: Freetown
Somalia
- Population: 15893219
- Region: Africa
- Capital: Mogadishu
South Africa
- Population: 59308690
- Region: Africa
- Capital: PretoriaBloemfonteinCape Town
South Sudan
- Population: 11193729
- Region: Africa
- Capital: Juba
Sudan
- Population: 43849269
- Region: Africa
- Capital: Khartoum
Tanzania
- Population: 59734213
- Region: Africa
- Capital: Dodoma
Togo
- Population: 8278737
- Region: Africa
- Capital: Lomé
Tunisia
- Population: 11818618
- Region: Africa
- Capital: Tunis
Uganda
- Population: 45741000
- Region: Africa
- Capital: Kampala
Western Sahara
- Population: 510713
- Region: Africa
- Capital: El Aaiún
Zambia
- Population: 18383956
- Region: Africa
- Capital: Lusaka
Zimbabwe
- Population: 14862927
- Region: Africa
- Capital: Harare